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Table 1 Properties of the core and geochemical characteristics of the oil used in the experimenta

From: An experimental investigation of geochromatography during secondary migration of petroleum performed under subsurface conditions with a real rock

Siltstone, Cadley A mine, Leics.

 

   Porosity

ca. 12%

   Permeability (brine)

0.01–0.02 mD

   Total carbon content

0.9%

   Total organic carbon content

0.4%

   Clay content (estimated XRD)

37%

Oil

 

   Saturated hydrocarbons

52.4%

   Aromatic hydrocarbons

29.4%

   Resins (NSO cmpds)

14.5%

   Asphaltenes

3.7%

Carbazole

0.9 μg g-1

   1-Methylcarbazole

1.6 μg g-1

   Benzo[a]carbazole

0.5 μg g-1

   Benzo[c]carbazole

0.2 μg g-1

   Total C0–C2 alkylcarbazoles

20.2 μg g-1

   Sum C2 alkylcarbazoles

15.4 μg g-1

Phenol

28.3 μg g-1

   o-Cresol

13.7 μg g-1

   m-Cresol

3.3 μg g-1

   p-Cresol

5.9 μg g-1

   2-Ethylphenol

3.5 μg g-1

   4-Ethylphenol

2.4 μg g -1

   2-Isopropylphenol

0.8 μg g-1

   3-Isopropylphenol

1.0 μg g -1

  1. aPrefixes C0, C1, C2, C3 refer to the number of alkyl carbon substituents on the basic phenol or carbazole nucleus.