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Table 1 Computed chemical properties of saturated CaCl2:2H2O solutions at 50-150°C and ~1 bar.

From: Modeling acid-gas generation from boiling chloride brines

Temperature

(°C)

log fHCl

(log bar)

pH1

Water Activity

Ionic Strength

(molal)

P 0 sat

(bar)3

PH2O

(bar)4

50

-5.5

3.0

5.7

0.174

35

0.124

0.022

75

-4.5

2.9

5.3

0.189

36

0.386

0.073

100

-3.7

2.8

4.9

0.200

39

1.014

0.203

125

-3.0

2.8

4.5

0.216

40

2.322

0.502

150

-2.5

2.9

4.2

0.235

42

4.762

1.119

  1. 1 pH defined as , with γ being the activity coefficient from the Pitzer model; 2 Also defined as pmH or p[H]; 3 NIST tables [37]; 4 Equation (5)