From: Metathesis in the generation of low-temperature gas in marine shales
Mowry 1 | |||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
time (hr) | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 |
C 1 | 3.42 | 2.96 | 2.26 | 2.15 | 2.11 | 2.42 | 1.53 | 1.23 | 0.94 | 1.02 | 1.19 |
C 2 | 0.87 | 0.83 | 0.53 | 0.52 | 0.58 | 0.68 | 0.42 | 0.34 | 0.39 | 0.34 | 0.32 |
C 3 | 5.00 | 2.69 | 0.90 | 0.72 | 0.65 | 0.62 | 0.41 | 0.37 | 0.25 | 0.24 | 0.29 |
i-C 4 | 25.74 | 12.65 | 3.16 | 1.84 | 1.09 | 0.61 | 0.31 | 0.20 | 0.10 | 0.10 | 0.10 |
n-C 4 | 29.01 | 14.29 | 2.99 | 1.90 | 1.28 | 0.92 | 0.53 | 0.26 | 0.31 | 0.25 | 0.26 |
CP | 12.55 | 6.87 | 1.34 | 0.91 | 0.64 | 0.37 | 0.24 | 0.17 | 0.08 | 0.08 | 0.08 |
i-C 5 | 72.07 | 37.75 | 8.26 | 5.18 | 3.26 | 1.88 | 1.01 | 0.38 | 0.25 | 0.25 | 0.08 |
n-C 5 | 54.42 | 28.27 | 5.31 | 3.44 | 2.23 | 1.38 | 0.81 | 0.37 | 0.24 | 0.28 | 0.27 |
Sum mol | 203.08 | 106.31 | 24.76 | 16.67 | 11.83 | 8.87 | 5.26 | 3.32 | 2.56 | 2.56 | 2.61 |
Sum wt | 13462 | 6987 | 1520 | 984 | 657 | 435 | 252 | 139 | 102 | 101 | 94 |
Product AMW | 66 | 66 | 61 | 59 | 56 | 49 | 48 | 42 | 40 | 40 | 36 |
log Q | 1.35 | 1.07 | 0.86 | 0.75 | 0.61 | 0.50 | 0.55 | 0.60 | 0.18 | 0.31 | 0.52 |
log Q* | 1.36 | 1.28 | 1.15 | 1.04 | 0.85 | 0.72 | 0.66 | 0.41 | 0.47 | 0.49 | 0.51 |
Mowry 2 | |||||||||||
time (hr) | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 |
C 1 | 2.78 | 2.70 | 2.08 | 1.72 | 1.73 | 1.61 | 1.69 | 0.98 | 1.15 | 0.88 | |
C 2 | 0.81 | 0.92 | 0.64 | 0.44 | 0.52 | 0.48 | 0.52 | 0.28 | 0.35 | 0.28 | |
C 3 | 9.31 | 4.34 | 1.19 | 0.79 | 0.68 | 0.54 | 0.53 | 0.25 | 0.29 | 0.24 | |
i-C 4 | 31.63 | 13.39 | 2.71 | 1.46 | 0.81 | 0.47 | 0.32 | 0.11 | 0.12 | 0.06 | |
n-C 4 | 43.35 | 18.12 | 3.49 | 1.94 | 1.29 | 0.88 | 0.71 | 0.29 | 0.34 | 0.27 | |
CP | 14.59 | 7.31 | 1.70 | 1.01 | 0.67 | 0.40 | 0.26 | 0.10 | 0.10 | 0.05 | |
i-C 5 | 80.07 | 37.15 | 8.27 | 4.61 | 2.77 | 1.58 | 1.01 | 0.24 | 0.26 | 0.18 | |
n-C 5 | 68.80 | 31.18 | 6.49 | 3.63 | 2.23 | 1.33 | 0.89 | 0.28 | 0.36 | 0.23 | |
Sum mol | 251.35 | 115.11 | 26.57 | 15.60 | 10.70 | 7.30 | 5.93 | 2.52 | 2.97 | 2.17 | |
Sum wt | 16568 | 7521 | 1646 | 936 | 602 | 381 | 281 | 102 | 120 | 84 | |
Product AMW | 66 | 65 | 62 | 60 | 56 | 52 | 47 | 41 | 40 | 39 | |
log Q | 1.59 | 1.14 | 0.78 | 0.84 | 0.64 | 0.58 | 0.52 | 0.49 | 0.45 | 0.43 | |
log Q* | 1.20 | 1.09 | 0.98 | 0.98 | 0.80 | 0.74 | 0.64 | 0.61 | 0.59 | 0.55 |