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Table 6 Rate parameters from Palandri and Kharaka [40].

From: Experimental Study of Cement - Sandstone/Shale - Brine - CO2Interactions

Phase

Neutral

Acid

Base

 

k25°C (mol/m2/s)

Ea (mol/KJ)

k25°C (mol/m2/s)

Ea (mol/KJ)

N

k25°C (mol/m2/s)

Ea (mol/KJ)

n

aBoehmite

-11.5

61.2

-7.7

47.5

0.99

-16.7

80.1

-0.78

Dolomite

-7.5

52.2

-3.2

36.1

0.50

   

bFe(OH)3

        

Ripedolite

-12.5

88

-11.1

88.0

0.50

   

Illite

-12.8

35

-11.0

23.6

0.34

-16.5

58.9

-0.40

Kaolinite

-13.2

22.2

-11.3

65.9

0.78

-17.0

17.9

-0.47

Low-albite

-12.6

69.8

-10.2

65.0

0.46

-15.6

71.0

-0.57

Quartz

-14.0

87.7

      

Siderite

-8.9

62.76

-3.8

45.0

0.90

   

Smectite

-12.8

35

-11.0

23.6

0.34

-16.5

58.9

-0.40

  1. aGibbsite dissolution rates were applied for boehmite. bFe(OH)3 rate was estimated from match to the solution chemistry normalized to mineral moles and is listed in Table 7.