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Table 1 Thermodynamic data used to produce the curves in Figure 1

From: Adsorption of dissolved aluminum on sapphire-c and kaolinite: implications for points of zero charge of clay minerals

Reaction Log K
Al3+ + H2O = AlOH2+ + H+ -4.950
Al3+ + 2 H2O = Al(OH)2+ + 2 H+ -10.590
Al3+ + 3 H2O = Al(OH)3 + 3 H+ -16.420
Al3+ + 4 H2O = Al(OH)4- + 4 H+ -22.870
Al(OH)3(am): Al(OH)3(s) + 3 H+ = Al3+ + 3 H2O 10.578
Gibbsite: Al(OH)3(s) + 3 H+ = Al3+ + 3 H2O 7.738
Kaolinite: Al2Si2O5(OH)4 + 6H+ = 2 Al3+ + 2 H4SiO4 + H2O 6.472
Sapphire (α-Corundum): Al2O3 + 6 H+ = 2 Al3+ + 3 H2O 18.301