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Table 1 Model ore-fluids for Mississippi Valley-type (MVT) and red-bed related base metal (RBRBM) deposits

From: Transport of Pb and Zn by carboxylate complexes in basinal ore fluids and related petroleum-field brines at 100 °C: the influence of pH and oxygen fugacity

Parameter

MVT Anderson [37]

MVT Giordano and Barnes [39]

MVT Sverjensky[41]

RBRBMaGiordano[76]

Composite ore-brine (this study)

T/°C

100

100

125

100

100

pH

5.7 to 6.7

6.8 to 7.8

4.5 to 5.5

5.5 to 6.5

variable

log ?1?

-48 to -51

-54 to -58

-50.5 to -51.5

-49 to -51

variable

log ∑msulfur

–2

-2

-4.6

-2

-2

log ∑mcarbonate

-1.37

-2 to -4

-1.52

-2.4

-2

3.0

(2.0)

2.76 (1.4)

2.0

3.0

3.0

(1.5)

1.67 (1.0)

(1.0)

2.81

 

(0.02)

0.012 (.007)

(0.01)

0.05

0.1

(0.05)

0.491 (.074)

(0.01)

0.2

 

(0.02)

0.056 (0.013)

(0.005)

0.1

Chlorinityb

99530

99530

93450

69050

97450

SalinityC

169 200

169 200

158 865

132480

179 270

Saturation

Galena

X

X

X

X

X

Sphalerite

X

X

 

X

X

Pyrite

 

X

X

 

xd

Hematite

X

  

x

xe

Magnetite

    

xf

Calcite

X

X

 

X

 

Dolomite

  

X

  

Quartz

 

X

X

X

X

K-Feldspar

 

X

  

X

Muscovite

 

X

   

Kaolinite

  

X

  
  1. aThe composition of this model ore fluid is a composite based on parameter values proposed by Rose,[23,24] Sverjensky,[31,32] and Branam and Ripley.[75] bChlorinity = Cl- concentration in mg L-1. Calculated from and assuming a fluid density of l.l g cm-3 cSalinity = total dissolved solids (TDS) in mg L-1. Calculated assuming a fluid density of l.l g cm-3. dPyrite stability field only. eHematite stability field only. fMagnetite stability field only.