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Table 7 Zinc speciation, as a function of pH and log along the 100 ppm Zn isopleth of the model composite ore-brine at 100°Cab

From: Transport of Pb and Zn by carboxylate complexes in basinal ore fluids and related petroleum-field brines at 100 °C: the influence of pH and oxygen fugacity

pH

log

Iron phasecsaturation

Cation

Chloride complexes

Sulfide complexes

Hydroxide complexes

Acetate complexes

Malonate complexes

Data set

8.00

-50.55

Hm

0.11

31.53

9.2 × 10-14

67.90

0.45

9.0 × 10-3

5

7.00

-50.35

Hm

0.28

81.15

3.8 × 10-12

17.30

1.22

0.02

4

5.00

-50.3

Hm

0.35

98.43

2.9 × 10-8

0.21

0.97

0.23

3

4.00

-50.3

Py

0.36

99.36

2.9 × 10-6

0.02

0.24

9.6 × 10-3

2

3.00

-50.3

Py

0.36

99.60

2.7 × 10-4

2.2 × 10-3

0.03

2.0 × 10-3

1

  1. aSpeciation for the indicated complexes is given as mol% of total Zn. bThe 100 ppm isopleth is illustrated in Fig. 3. cSaturation with respect to hematite (Hm), pyrite (Py), or magnetite (Mt).