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Table 8 Zinc speciation, as a function of pH and log along the 0.01 ppm Zn isopleth of the model composite ore-brine at 100°Cab

From: Transport of Pb and Zn by carboxylate complexes in basinal ore fluids and related petroleum-field brines at 100 °C: the influence of pH and oxygen fugacity

pH

log

Iron phasecsaturation

Cation

Chloride complexes

Sulfide complexes

Hydroxide complexes

Acetate complexes

Malonate complexes

Data set

8.00

-52.55

Hm

0.11

31.53

9.3 × 10-6

67.90

0.45

9.0 × 10-3

7

7.00

-52.35

Hm

0.28

81.15

3.8 × 10-4

17.30

1.22

0.02

6

6.00

-52.30

Py

0.34

96.19

0.03

2.07

1.33

0.03

5

4.75

-52.90

Py

0.04

12.36

87.48

0.02

0.10

2.5 × 10-3

4

5.78

-54.00

Py

3.9 × 10-4

0.11

99.89

1.4 × 10-3

1.5 × 10-3

3.0 × 10-5

3

6.40

-55.00

Py

2.4 × 10-5

6.7 × 10-3

99.99

3.6 × 10-4

9.6 × 10-5

1.9 × 10-6

2

6.50

-56.00

Py

1.7 × 10-5

4.8 × 10-3

99.99

3.2 × 10-4

6.9 × 10-5

1.4 × 10-6

1

  1. aSpeciation for the indicated complexes is given as mol% of total Zn. bThe 0.01 ppm isopleth is illustrated in Fig. 3. cSaturation with respect to hematite (Hm), pyrite (Py), or magnetite (Mt).