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Table 4 Δε(Eq. 11) estimated from solubility product quotients of portlandite in various media at 25°C

From: Estimation of medium effects on equilibrium constants in moderate and high ionic strength solutions at elevated temperatures by using specific interaction theory (SIT): Interaction coefficients involving Cl, OH- and Ac-up to 200°C and 400 bars

Medium

Δε(Eq. 11) (± 2σ)

Ionic Strength Range, m

Linearity of Fitting (Square of Linear Correlation Coefficient, R2)

Experimental Data Source for Estimation

NaAc

0.07 ± 0.02

0.2–4.9

0.9619

Johnston and Grove [40]

SrCl2

-0.06 ± 0.02

0.2–4.0

0.9138

 

BaCl2

-0.035 ± 0.008

0.1–4.9

0.8881