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Table 2 Solution analyses for strontium sorption to amorphous silica in air, I = 0.1 M NaCl and T = 25°C.

From: Surface complexation model for strontium sorption to amorphous silica and goethite

Final pH

Surface Area m2L-1

Initial [Sr] M

Final [Sr] M

%Sr sorbed

Γ Sr sorbed Mol m-2

Total Dissolved Carbonate M

Total Sr = 10-3 M aged for 2 days

 

± 5%

  

6.67

11073

9.98 × 10-4

1.01 × 10-3

-1.5

-1.31 × 10-9

not measured

6.72

11098

1.00 × 10-3

1.02 × 10-3

-1.6

-1.43 × 10-9

not measured

6.80

11086

9.98 × 10-4

1.03 × 10-3

-3.6

-3.27 × 10-9

not measured

6.90

11060

9.94 × 10-4

1.02 × 10-3

-2.5

-2.21 × 10-9

not measured

7.19

11012

9.91 × 10-4

1.05 × 10-3

-6.1

-5.46 × 10-9

not measured

7.89

10724

9.66 × 10-4

9.35 × 10-4

3.2

2.89 × 10-9

not measured

8.32

10522

9.45 × 10-4

8.00 × 10-4

15.4

1.38 × 10-8

not measured

8.65

10237

9.23 × 10-4

5.28 × 10-4

42.7

3.85 × 10-8

not measured

9.58

9224

8.33 × 10-4

3.22 × 10-5

96.1

8.68 × 10-8

not measured

6.54

11016

1.00 × 10-3

1.02 × 10-3

-1.5

-1.36 × 10-9

1.72 × 10-5

6.61

11026

1.00 × 10-3

1.01 × 10-3

-0.4

-3.41 × 10-10

3.61 × 10-5

6.70

11004

9.97 × 10-4

1.01 × 10-3

-0.9

-8.38 × 10-10

3.34 × 10-5

6.73

11003

9.99 × 10-4

9.99 × 10-4

0.0

1.79 × 10-12

3.69 × 10-6

7.14

10961

9.93 × 10-4

9.69 × 10-4

2.4

2.19 × 10-9

2.67 × 10-5

7.72

10758

9.77 × 10-4

8.82 × 10-4

9.7

8.76 × 10-9

1.72 × 10-4

8.65

10327

9.36 × 10-4

5.85 × 10-4

37.5

3.40 × 10-8

3.52 × 10-4

8.98

10019

9.04 × 10-4

4.33 × 10-4

52.1

4.70 × 10-8

4.44 × 10-4

9.57

9565

8.65 × 10-4

2.20 × 10-4

74.6

6.75 × 10-8

5.64 × 10-4

7.98

10670

9.68 × 10-4

8.49 × 10-4

12.2

1.11 × 10-8

1.04 × 10-4

8.06

10590

9.68 × 10-4

8.60 × 10-4

11.1

1.01 × 10-8

8.95 × 10-5

8.82

10187

9.27 × 10-4

5.25 × 10-4

43.3

3.95 × 10-8

1.05 × 10-4

8.84

10272

9.27 × 10-4

5.05 × 10-4

45.5

4.11 × 10-8

1.54 × 10-4

8.85

10228

9.28 × 10-4

5.30 × 10-4

42.8

3.89 × 10-8

1.46 × 10-4

8.91

10160

9.27 × 10-4

5.14 × 10-4

44.6

4.07 × 10-8

2.13 × 10-4

9.16

9992

9.05 × 10-4

3.86 × 10-4

57.3

5.20 × 10-8

1.53 × 10-4

9.19

9967

9.06 × 10-4

3.91 × 10-4

56.8

5.17 × 10-8

1.52 × 10-4

9.26

9767

8.88 × 10-4

3.77 × 10-4

57.5

5.23 × 10-8

3.47 × 10-5

9.38

9961

9.00 × 10-4

3.40 × 10-4

62.2

5.62 × 10-8

2.40 × 10-5

9.44

9849

8.96 × 10-4

3.24 × 10-4

63.8

5.81 × 10-8

9.92 × 10-5

9.53

9822

8.88 × 10-4

2.83 × 10-4

68.2

6.16 × 10-8

7.95 × 10-5

9.54

9787

8.88 × 10-4

2.72 × 10-4

69.4

6.30 × 10-8

1.85 × 10-4

9.72

9461

8.58 × 10-4

2.29 × 10-4

73.3

6.65 × 10-8

1.82 × 10-4

Total Sr = 10-4 M aged for 2 days

 

± 5%

  

7.08

11079

1.00 × 10-4

1.04 × 10-4

-3.5

-3.15 × 10-10

not measured

6.41

11063

1.01 × 10-4

1.06 × 10-4

-5.1

-4.57 × 10-10

not measured

6.92

11002

1.00 × 10-4

1.09 × 10-4

-8.9

-8.11 × 10-10

not measured

7.02

10966

9.99 × 10-5

1.05 × 10-4

-5.3

-4.79 × 10-10

not measured

7.26

10922

9.88 × 10-5

9.88 × 10-5

0.0

4.05 × 10-13

not measured

7.50

10712

9.70 × 10-5

9.10 × 10-5

6.2

5.61 × 10-10

not measured

8.57

10078

9.14 × 10-5

5.30 × 10-5

42.2

3.81 × 10-9

not measured

9.33

9404

8.51 × 10-5

2.15 × 10-5

75.2

6.77 × 10-9

not measured

9.86

8585

7.81 × 10-5

9.13 × 10-6

88.7

8.03 × 10-9

not measured

Total Sr = 10-5 M aged for 2 days

 

± 5%

  

6.21

10913

1.05 × 10-5

1.07 × 10-5

-1.4

-1.39 × 10-11

not measured

6.40

11302

1.06 × 10-5

1.04 × 10-5

1.2

1.13 × 10-11

not measured

6.70

11458

1.06 × 10-5

1.03 × 10-5

2.0

1.88 × 10-11

not measured

7.15

11367

1.05 × 10-5

1.01 × 10-5

3.8

3.54 × 10-11

not measured

6.95

10918

1.05 × 10-5

1.04 × 10-5

1.0

9.75 × 10-12

not measured

7.60

10844

1.03 × 10-5

9.45 × 10-6

8.5

8.10 × 10-11

not measured

7.91

10811

1.03 × 10-5

8.71 × 10-6

15.1

1.43 × 10-10

not measured

8.92

10175

9.72 × 10-6

4.36 × 10-6

55.2

5.27 × 10-10

not measured

9.58

9544

9.12 × 10-6

1.85 × 10-6

79.7

7.62 × 10-10

not measured

Total Sr = 10-6 M aged for 2 days

 

± 10%

  

6.52

11049

1.59 × 10-6

1.65 × 10-6

-3.9

-5.60 × 10-12

not measured

6.64

11038

1.59 × 10-6

1.53 × 10-6

3.4

4.84 × 10-12

not measured

6.71

11025

1.58 × 10-6

1.50 × 10-6

5.4

7.78 × 10-12

not measured

6.81

11019

1.58 × 10-6

1.48 × 10-6

6.7

9.56 × 10-12

not measured

6.88

11030

1.58 × 10-6

1.51 × 10-6

4.5

6.42 × 10-12

not measured

7.62

10867

1.56 × 10-6

1.42 × 10-6

8.8

1.26 × 10-11

not measured

8.39

10590

1.52 × 10-6

1.13 × 10-6

25.3

3.64 × 10-11

not measured

9.06

10235

1.47 × 10-6

7.21 × 10-7

50.9

7.32 × 10-11

not measured

9.59

9873

1.42 × 10-6

3.89 × 10-7

72.5

1.04 × 10-10

not measured

Total Sr = 7 × 10-7 M aged for 2 days

 

± 20%

  

6.89

11022

6.81 × 10-7

6.46 × 10-7

5.1

3.14 × 10-12

not measured

6.50

11070

6.83 × 10-7

6.57 × 10-7

3.8

2.31 × 10-12

not measured

6.70

11016

6.80 × 10-7

6.82 × 10-7

-0.3

-2.12 × 10-13

not measured

6.43

11013

6.80 × 10-7

7.18 × 10-7

-5.6

-3.44 × 10-12

not measured

7.56

10685

6.59 × 10-7

5.63 × 10-7

14.7

9.05 × 10-12

not measured

7.73

10508

6.49 × 10-7

5.15 × 10-7

20.6

1.27 × 10-11

not measured

8.52

9978

6.16 × 10-7

3.34 × 10-7

45.7

2.82 × 10-11

not measured

9.05

9538

5.89 × 10-7

1.71 × 10-7

70.9

4.38 × 10-11

not measured

9.53

8920

5.50 × 10-7

8.10 × 10-8

85.3

5.26 × 10-11

not measured