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Table 8 EXAFS fit results for strontium sorbed to amorphous silica and goethite (R, N, σ2 and ΔE0 adjusted in fits).

From: Surface complexation model for strontium sorption to amorphous silica and goethite

Electrolyte

pH

T(K)

Sr-Za

R(Ã…)

N

σ2(Å2)

ΔE0(eV)

Amorphous Silica, Srtotal = 10-3 M

0.1 M Na Cl

8.1

20

Sr-O

2.60

10.0

0.0081

-4.9

0.1 M Na Cl

8.9

20

Sr-O

2.60

10.1

0.0087

-5.4

0.1 M Na Cl

9.4

25

Sr-O

2.60

10.6

0.0094

-6.1

0.1 M Na Cl

9.7

16

Sr-O

2.60

10.3

0.0086

-5.9

Goethitec, Srtotal = 10-3 M

0.1 M Na Cl

8.5

20

Sr-O

2.63

10.1

0.0084

-6.6

   

Sr-C

3.05

3.8

0.0018

 
   

Sr-Sr

4.14

3.4

0.0021

 
   

Sr-Sr

4.28

1.4

0.0005

 
   

Sr-Sr

4.90

3.3

0.0031

 

0.1 M Na Cl

8.7

RT

Sr-O

2.58

8.3

0.0126

-5.6

0.1 M Na Cl

9.3

15

Sr-O

2.61

9.8

0.0081

-5.0

0.1 M NaNO3

9.9

12

Sr-O

2.60

9.1

0.0077

-6.9

  1. aZ = backscattering atom.
  2. bScale factor (S02) = 0.92
  3. cGoethite samples and analyses are from Sahai et al. [26]