Skip to main content

Table 1 Least square analysis of Cr K-edge XAS spectra

From: Effects of common groundwater ions on chromate removal by magnetite: importance of chromate adsorption

Sample

 

Cr(VI)–O

Cr(III)–O

Cr–Cr/Fe

Cr–Cr/Fe

% Cr(VI)

% Cr(III)

R-factor

pH 4 (± 0.02)

CN

4a

6a

1.3 (3)

0.4 (2)

   

0.016 M

R

1.60 (1)

1.99 (1)

3.03 (2)

3.44 (3)

54 (±7)

46 (±7)

0.017

Na2SO4

σ2

0.005 (2)

0.003 (1)

0.007a

0.002 (1)

   

pH 4 (± 0.02)

CN

4a

6a

1.2 (1)

0.6 (3)

   

0.01 M

R

1.65 (1)

1.98 (1)

3.00 (3)

3.48 (2)

49 (±7)

51 (±7)

0.030

NaNO3

σ2

0.008 (4)

0.016 (1)

0.007a

0.002 (1)

   
  1. Estimated errors for CN: ±20 % and R: ±0.01Å [12]
  2. CN Coordination number, R inter atomic distances (Å), σ 2 Debye–Waller factor (Å2)
  3. a Fixed parameters for the first Cr–Cr/Fe shell is according to the study [12]