From: A study on the dissolution rates of K-Cr(VI)-jarosites: kinetic analysis and implications
[NaOH]/mol L−1 | pH | T/K | CrO4/mola | [OH−]/mol L−1 | d0/µmb | tind/min | kexp/min −1 | tr/min |
---|---|---|---|---|---|---|---|---|
0.100 | 12.29 | 323.15 | 0.77 | 0.1023 | 38 | 0.7 | 0.5929 | 2.5 |
0.050 | 12.14 | 323.15 | 0.77 | 0.0724 | 38 | 1.6 | 0.2138 | 4.5 |
0.030 | 11.81 | 323.15 | 0.77 | 0.0339 | 38 | 3.2 | 0.1284 | 10.0 |
0.010 | 11.49 | 323.15 | 0.77 | 0.0162 | 38 | 6.8 | 0.0597 | 20.0 |
0.006 | 11.14 | 323.15 | 0.77 | 0.0072 | 38 | 16.5 | 0.0346 | 30.0 |
0.001 | 10.37 | 323.15 | 0.77 | 0.0012 | 38 | 75.0 | 0.0197 | 115.0 |
0.300 | 13.36 | 303.15 | 0.77 | 0.3342 | 38 | 0.86 | 0.2735 | 4.0 |
0.200 | 13.15 | 303.15 | 0.77 | 0.2061 | 38 | 1.69 | 0.1474 | 5.0 |
0.100 | 12.94 | 303.15 | 0.77 | 0.1271 | 38 | 3.18 | 0.0962 | 16.0 |
0.050 | 12.45 | 303.15 | 0.77 | 0.0397 | 38 | 8.63 | 0.0397 | 30.0 |
0.025 | 12.18 | 303.15 | 0.77 | 0.0221 | 38 | 19.04 | 0.0207 | 50.0 |
0.010 | 11.88 | 303.15 | 0.77 | 0.0111 | 38 | 55.2 | 0.0082 | 160.0 |
0.007 | 11.67 | 303.15 | 0.77 | 0.0065 | 38 | 137.49 | 0.0051 | 280.0 |
0.003 | 11.38 | 303.15 | 0.77 | 0.0035 | 38 | 253.74 | 0.0038 | 420.0 |
0.001 | 10.79 | 303.15 | 0.77 | 0.0009 | 38 | 1342.41 | 0.0011 | 2100.0 |
0.050 | 12.88 | 293.15 | 0.77 | 0.05200 | 38 | 26.0 | 0.0200 | 70.0 |
0.050 | 12.62 | 298.15 | 0.77 | 0.04200 | 38 | 12.5 | 0.0251 | 40.0 |
0.050 | 12.18 | 308.15 | 0.77 | 0.03100 | 38 | 4.4 | 0.0455 | 18.0 |
0.050 | 12.04 | 313.15 | 0.77 | 0.03100 | 38 | 3.5 | 0.0791 | 14.0 |
0.050 | 11.92 | 318.15 | 0.77 | 0.03300 | 38 | 2.0 | 0.1464 | 10.0 |
0.050 | 11.87 | 323.15 | 0.77 | 0.03900 | 38 | 1.7 | 0.1881 | 7.0 |
0.050 | 11.51 | 328.15 | 0.77 | 0.02300 | 38 | 0.8 | 0.2103 | 3.7 |
0.050 | 11.39 | 333.15 | 0.77 | 0.02300 | 38 | 0.4 | 0.3248 | 2.8 |
0.050 | 11.04 | 343.15 | 0.77 | 0.01700 | 38 | 0.1 | 0.5794 | 2.3 |
0.010 | 11.88 | 303.15 | 0.77 | 0.01096 | 38 | 58.0 | 0.0082 | 160.0 |
0.010 | 11.79 | 313.15 | 0.77 | 0.01778 | 38 | 20.1 | 0.0299 | 51.0 |
0.010 | 11.34 | 323.15 | 0.77 | 0.01148 | 38 | 9.1 | 0.0484 | 24.0 |
0.010 | 10.91 | 333.15 | 0.77 | 0.00759 | 38 | 3.1 | 0.0705 | 16.0 |
0.010 | 10.68 | 343.15 | 0.77 | 0.00741 | 38 | 1.3 | 0.1752 | 5.0 |
0.050 | 12.53 | 303.15 | 0.77 | 0.049 | 75 | 7.5 | 0.02 | 24.0 |
0.050 | 12.54 | 303.15 | 0.77 | 0.050 | 53 | 9.81 | 0.0311 | 27.0 |
0.050 | 12.55 | 303.15 | 0.77 | 0.051 | 44 | 8.63 | 0.034 | 25.0 |
0.050 | 12.53 | 303.15 | 0.77 | 0.049 | 38 | 9.3 | 0.0397 | 30.0 |
0.050 | 12.52 | 303.15 | 0.77 | 0.048 | 25 | 9.1 | 0.0632 | 28.0 |
0.050 | 12.54 | 303.15 | 1.99 | 0.0500 | 38 | 6.9 | 0.0373 | 27.0 |
0.050 | 12.68 | 303.15 | 1.57 | 0.0555 | 38 | 2.3 | 0.0358 | 25.0 |
0.050 | 12.68 | 303.15 | 1.02 | 0.0555 | 38 | 2.8 | 0.0373 | 25.0 |
0.050 | 12.45 | 303.15 | 0.77 | 0.0411 | 38 | 8.6 | 0.0397 | 30.0 |
0.050 | 12.53 | 303.15 | 0.12 | 0.049 | 38 | 4.2 | 0.0369 | 24.0 |
0.050 | 12.48 | 303.15 | 0.09 | 0.0555 | 38 | 6.9 | 0.0367 | 27.0 |
0.050 | 12.69 | 303.15 | 0.00 | 0.0568 | 38 | 4.3 | 0.0392 | 25.0 |