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Table 3 Dissolution rates of ZnS (RZnS) and PbS (RPbS) in sulfide samples during 1–30 h

From: Onboard experiment investigating metal leaching of fresh hydrothermal sulfide cores into seawater

Sample ID

  

RZnS (mol m−2 s−1)

RPbS (mol m−2 s−1)

  

RZnS (mol m−2 s−1)

RPbS (mol m−2 s−1)

CKL-1

Anoxic

5 °C

−3.6 × 10−11

(−3.5 to − 3.7 × 10−11)

−3.0 × 10−11

(−2.9 to − 3.1 × 10−11)

Oxic

5 °C

−8.7 × 10−11

(−8.6 to − 8.9 × 10−11)

−2.8 × 10−11

(−2.7 to − 2.9 × 10−11)

20 °C

−2.4 × 10−11

(−2.3 to − 2.4 × 10−11)

−2.1 × 10−11

(−2.0 to − 2.1 × 10−11)

20 °C

−7.2 × 10−11

(−7.1 to − 7.3 × 10−11)

−2.7 × 10−11

(−2.6 to − 2.7 × 10−11)

CKL-2

Anoxic

5 °C

6.0 × 10−10

(4.7 to 7.2 × 10−10)

−4.8 × 10−11

(−4.1 to − 5.5 × 10−11)

Oxic

5 °C

−1.5 × 10−9

(−1.4 to − 1.6 × 10−9)

−4.0 × 10−10

(−3.8 to − 4.3 × 10−10)

20 °C

1.4 × 10−9

(1.1 to 1.6 × 10−9)

1.8 × 10−10

(1.7 to 1.9 × 10−10)

20 °C

−1.5 × 10−9

(−1.2 to − 1.8 × 10−9)

−6.4 × 10−10

(−6.2 to − 6.7 × 10−10)

CKL-3

Anoxic

5 C

3.4 × 10−9

(3.2 to 3.5 × 10−9)*

5.7 × 10−8

(4.1 to 7.4 × 10−8)*

Oxic

5 °C

1.1 × 10−8

(1.0 to 1.1 × 10−8)*

 − 3.1 × 10−8

(−2.5 to − 3.7 × 10−8)*

20 °C

8.1 × 10−9

(7.9 to 8.4 × 10−9)*

2.5 × 10−7

(2.3 to 2.8 × 10−7)*

20 °C

4.4 × 10−8

(4.3 to 4.4 × 10−8)*

2.9 × 10−7

(2.8 to 2.9 × 10−7)*

CKL-4

Anoxic

5 °C

4.9 × 10−10

(3.4 to 6.4 × 10−10)

−3.3 × 10−9

(−2.9 to − 3.8 × 10−9)

Oxic

5 °C

1.7 × 10−9

(1.6 to 1.7 × 10−9)

−1.3 × 10−9

(−1.3 to − 1.4 × 10−9)

20 °C

5.6 × 10−10

(4.7 to 6.4 × 10−10)

−1.4 × 10−9

(−1.4 to − 1.6 × 10−9)

20 °C

3.9 × 10−9

(3.8 to 4.0 × 10−9)

2.7 × 10−10

(2.6 to 2.9 × 10−10)

  1. The RZnS and RPbS values with an asterisk* for CLK-3 were calculated during 1–18 h because the pH decreased greatly to 4.5 under oxic conditions at 20 °C during 18–30 h. The values represent means (ranges) of duplicates