|
HW1
| | | | | | | | | |
---|
n
|
7
| |
6
| | | | | | | |
---|
|
Ta-Pyr
|
Stdev
|
Melt
|
Stdev
|
D Ta-pyr HW1
|
Stdev
| | | | |
---|
Li
|
1.0
|
0.1
|
12.7
|
0.3
|
0.08
|
0.01
| | | | |
Sc
|
205
|
22
|
1100
|
14
|
0.19
|
0.02
| | | | |
Mn
|
101
|
11
|
290
|
1
|
0.35
|
0.04
| | | | |
Co
|
205
|
37
|
1290
|
10
|
0.16
|
0.03
| | | | |
Ni
|
76
|
16
|
641
|
4
|
0.12
|
0.03
| | | | |
Ga
|
21
|
11
|
791
|
13
|
0.03
|
0.01
| | | | |
Ge
|
77
|
10
|
250
|
4
|
0.31
|
0.04
| | | | |
Sr
|
187
|
3
|
477
|
3
|
0.39
|
0.01
| | | | |
Y
|
708
|
105
|
707
|
4
|
1.0
|
0.1
| | | | |
Zr
|
896
|
130
|
906
|
8
|
1.0
|
0.1
| | | | |
Nb
|
999
|
92
|
777
|
12
|
1.3
|
0.1
| | | | |
Mo
|
0.20
|
0.18
|
12.8
|
0.2
|
0.02
|
0.01
| | | | |
Ba
|
33
|
9
|
736
|
7
|
0.04
|
0.01
| | | | |
La
|
1111
|
173
|
448
|
6
|
2.5
|
0.4
| | | | |
Ce
|
1070
|
361
|
191
|
3
|
5.6
|
1.9
| | | | |
Nd
|
1695
|
389
|
490
|
8
|
3.5
|
0.8
| | | | |
Sm
|
1408
|
323
|
466
|
4
|
3.0
|
0.7
| | | | |
Gd
|
675
|
127
|
317
|
3
|
2.1
|
0.4
| | | | |
Dy
|
565
|
91
|
372
|
2
|
1.5
|
0.2
| | | | |
Yb
|
324
|
37
|
487
|
3
|
0.7
|
0.1
| | | | |
Lu
|
558
|
64
|
1048
|
11
|
0.5
|
0.1
| | | | |
Hf
|
1390
|
299
|
782
|
14
|
1.8
|
0.4
| | | | |
Ta
|
590,712
|
27,309
|
121,645
|
5874
|
4.9
|
0.3
| | | | |
Th
|
0.5
|
0.2
|
0.06
|
0.01
|
7.8
|
3.1
| | | | |
U
|
1.6
|
0.3
|
4.0
|
0.1
|
0.4
|
0.1
| | | | |
|
HW2
| | | | | | | | | |
---|
n
|
8
| |
6
| | | | | | | |
---|
|
Ta-Pyr
|
Stdev
|
Melt
|
Stdev
|
D Ta-pyr HW2
|
Stdev
| | | | |
---|
Li
|
1.4
|
0.2
|
14.3
|
0.4
|
0.10
|
0.02
| | | | |
Sc
|
187
|
25
|
985
|
10
|
0.19
|
0.03
| | | | |
Mn
|
105
|
4
|
282
|
7
|
0.37
|
0.02
| | | | |
Co
|
208
|
18
|
1197
|
12
|
0.17
|
0.01
| | | | |
Ni
|
77
|
11
|
581
|
6
|
0.13
|
0.02
| | | | |
Ga
|
18
|
5
|
705
|
9
|
0.03
|
0.01
| | | | |
Ge
|
70
|
8
|
60
|
2
|
1.18
|
0.13
| | | | |
Sr
|
180
|
3
|
448
|
5
|
0.40
|
0.01
| | | | |
Y
|
678
|
73
|
674
|
16
|
1.01
|
0.11
| | | | |
Zr
|
834
|
116
|
933
|
16
|
0.89
|
0.13
| | | | |
Nb
|
899
|
45
|
882
|
10
|
1.02
|
0.05
| | | | |
Mo
|
0.09
|
0.04
|
6.2
|
0.2
|
0.015
|
0.007
| | | | |
Ba
|
30
|
4
|
660
|
7
|
0.05
|
0.01
| | | | |
La
|
1067
|
74
|
481
|
5
|
2.2
|
0.2
| | | | |
Ce
|
1053
|
203
|
240
|
4
|
4.4
|
0.9
| | | | |
Nd
|
1693
|
212
|
543
|
7
|
3.1
|
0.4
| | | | |
Sm
|
1388
|
178
|
503
|
8
|
2.8
|
0.4
| | | | |
Gd
|
662
|
74
|
329
|
5
|
2.0
|
0.2
| | | | |
Dy
|
550
|
57
|
371
|
6
|
1.5
|
0.2
| | | | |
Yb
|
318
|
30
|
450
|
7
|
0.7
|
0.1
| | | | |
Lu
|
545
|
45
|
964
|
15
|
0.57
|
0.05
| | | | |
Hf
|
1326
|
202
|
848
|
18
|
1.6
|
0.2
| | | | |
Ta
|
603,553
|
6796
|
167,305
|
2991
|
3.6
|
0.1
| | | | |
Th
|
0.5
|
0.1
|
0.080
|
0.004
|
5.9
|
1.5
| | | | |
U
|
0.9
|
0.1
|
3.56
|
0.03
|
0.26
|
0.02
| | | | |
|
HW3
| | | | | | | | | |
---|
n
|
6
| |
5
| | | | | | | |
---|
|
Ta-Pyr
|
Stdev
|
Melt
|
Stdev
|
D Ta-pyr HW3
|
Stdev
| | | | |
---|
Li
|
3.2
|
0.6
|
68
|
21
|
0.05
|
0.02
| | | | |
Sc
|
112.8
|
48.9
|
1053
|
333
|
0.11
|
0.06
| | | | |
Mn
|
66.5
|
19.5
|
517
|
152
|
0.13
|
0.05
| | | | |
Co
|
109.5
|
43.9
|
3013
|
988
|
0.04
|
0.02
| | | | |
Ni
|
33.4
|
18.1
|
1409
|
456
|
0.024
|
0.015
| | | | |
Ga
|
10.5
|
1.2
|
1915
|
608
|
0.005
|
0.002
| | | | |
Ge
|
85.3
|
8.3
|
1340
|
419
|
0.06
|
0.02
| | | | |
Sr
|
196.5
|
6.5
|
904
|
291
|
0.22
|
0.07
| | | | |
Y
|
717.7
|
41.7
|
235
|
69
|
3.1
|
0.9
| | | | |
Zr
|
665.9
|
127.1
|
208
|
59
|
3.2
|
1.1
| | | | |
Nb
|
831.0
|
13.7
|
487
|
148
|
1.7
|
0.5
| | | | |
Mo
|
1.2
|
0.1
|
70
|
23
|
0.017
|
0.006
| | | | |
Ba
|
34.1
|
2.2
|
1843
|
570
|
0.018
|
0.006
| | | | |
La
|
1417
|
231
|
509
|
154
|
2.8
|
1.0
| | | | |
Ce
|
1527
|
269
|
87
|
24
|
17.6
|
5.8
| | | | |
Nd
|
2235
|
305
|
332
|
93
|
6.7
|
2.1
| | | | |
Sm
|
1770
|
171
|
251
|
71
|
7.1
|
2.1
| | | | |
Gd
|
778
|
35
|
138
|
39
|
5.6
|
1.6
| | | | |
Dy
|
608
|
18
|
138
|
40
|
4.4
|
1.3
| | | | |
Yb
|
304
|
31
|
148
|
43
|
2.0
|
0.6
| | | | |
Lu
|
493
|
66
|
319
|
94
|
1.5
|
0.5
| | | | |
Hf
|
1054
|
300
|
367
|
104
|
2.9
|
1.2
| | | | |
Ta
|
589,199
|
9317
|
87,900
|
24,870
|
6.7
|
1.9
| | | | |
Th
|
0.8
|
0.2
|
0.10
|
0.03
|
7.8
|
3.0
| | | | |
U
|
1.5
|
0.3
|
12
|
4
|
0.12
|
0.04
| | | | |
|
SE_Pyro3
| | | | | | | | | |
---|
n
|
5
| |
5
| | | | | | | |
---|
|
Nb-pyr
|
Stdev
|
Melt
|
stdev
|
D Nb-pyr/melt SE3
|
Stdev
| | | | |
---|
Li
|
3.5
|
0.3
|
13
|
1
|
0.27
|
0.03
| | | | |
Sc
|
315
|
151
|
1815
|
45
|
0.17
|
0.08
| | | | |
Mn
|
102
|
34
|
482
|
4
|
0.21
|
0.07
| | | | |
Co
|
298
|
157
|
1852
|
96
|
0.16
|
0.09
| | | | |
Ni
|
158
|
90
|
977
|
47
|
0.16
|
0.09
| | | | |
Ga
|
196
|
104
|
1125
|
64
|
0.17
|
0.09
| | | | |
Ge
|
40
|
3
|
50
|
28
|
0.8
|
0.5
| | | | |
Sr
|
547
|
10
|
618
|
12
|
0.88
|
0.02
| | | | |
Y
|
893
|
53
|
1400
|
60
|
0.64
|
0.05
| | | | |
Zr
|
697
|
139
|
2050
|
74
|
0.34
|
0.07
| | | | |
Nb
|
489,667
|
38,502
|
273,134
|
6537
|
1.8
|
0.1
| | | | |
Mo
|
10
|
1
|
27
|
5
|
0.37
|
0.09
| | | | |
Ba
|
265
|
68
|
944
|
18
|
0.28
|
0.07
| | | | |
La
|
1895
|
259
|
911
|
74
|
2
|
0.3
| | | | |
Ce
|
994
|
70
|
670
|
34
|
1.5
|
0.1
| | | | |
Nd
|
2376
|
314
|
1223
|
82
|
1.9
|
0.3
| | | | |
Sm
|
1791
|
169
|
1098
|
56
|
1.6
|
0.2
| | | | |
Gd
|
843
|
55
|
678
|
34
|
1.2
|
0.1
| | | | |
Dy
|
665
|
18
|
737
|
34
|
0.9
|
0.05
| | | | |
Yb
|
396
|
51
|
820
|
30
|
0.48
|
0.06
| | | | |
Lu
|
762
|
133
|
1847
|
81
|
0.41
|
0.07
| | | | |
Hf
|
901
|
105
|
1980
|
116
|
0.45
|
0.06
| | | | |
Ta
|
4361
|
947
|
1142
|
100
|
3.8
|
0.9
| | | | |
Th
|
167
|
6
|
196
|
11
|
0.85
|
0.06
| | | | |
U
|
23
|
12
|
108
|
31
|
0.2
|
0.1
| | | | |
|
SE_Pyro4
| | | | | | | | | |
---|
n
|
5
| |
5
| | | | | | | |
---|
|
Nb-pyr
|
Stdev
|
melt
|
Stdev
|
D Nb-pyr/melt SE4
|
Stdev
| | | | |
---|
Li
|
5.3
|
0.4
|
11.7
|
0.5
|
0.97
|
0.09
| | | | |
Sc
|
551
|
182
|
1822
|
18
|
0.82
|
0.27
| | | | |
Mn
|
127
|
59
|
514
|
3
|
0.7
|
0.3
| | | | |
Co
|
363
|
270
|
2034
|
52
|
0.58
|
0.43
| | | | |
Ni
|
188
|
125
|
1032
|
25
|
0.6
|
0.4
| | | | |
Ga
|
196
|
147
|
1008
|
23
|
0.5
|
0.4
| | | | |
Ge
|
123
|
67
|
288
|
191
|
2.3
|
2.0
| | | | |
Sr
|
568
|
18
|
606
|
18
|
1.31
|
0.06
| | | | |
Y
|
825
|
168
|
1421
|
24
|
1.10
|
0.20
| | | | |
Zr
|
1180
|
190
|
2058
|
47
|
1.20
|
0.20
| | | | |
Nb
|
481,096
|
60,016
|
268,189
|
9708
|
1.50
|
0.20
| | | | |
Mo
|
8.5
|
0.8
|
18
|
4
|
0.8
|
0.2
| | | | |
Ba
|
339
|
108
|
962
|
20
|
0.9
|
0.3
| | | | |
La
|
1916
|
147
|
841
|
21
|
1.6
|
0.1
| | | | |
Ce
|
932
|
59
|
643
|
10
|
1.43
|
0.09
| | | | |
Nd
|
2359
|
141
|
1176
|
28
|
1.6
|
0.1
| | | | |
Sm
|
1681
|
94
|
1065
|
21
|
1.47
|
0.09
| | | | |
Gd
|
784
|
73
|
668
|
13
|
1.40
|
0.10
| | | | |
Dy
|
609
|
91
|
739
|
15
|
1.20
|
0.20
| | | | |
Yb
|
379
|
118
|
835
|
14
|
0.90
|
0.30
| | | | |
Lu
|
753
|
279
|
1919
|
64
|
0.90
|
0.30
| | | | |
Hf
|
1561
|
247
|
1997
|
70
|
1.4
|
0.2
| | | | |
Ta
|
3862
|
1055
|
1084
|
85
|
1.6
|
0.5
| | | | |
Th
|
199
|
22
|
189
|
4
|
1.41
|
0.2
| | | | |
U
|
38
|
25
|
133
|
44
|
0.91
|
0.7
| | | | |
|
SE_Pyro5
| | | | | | | | | |
---|
n
|
5
| |
5
| | | | | | | |
---|
|
Fer
|
Stdev
|
melt
|
Stdev
|
D fer/melt SE5
|
Stdev
| | | | |
---|
Li
|
4.2
|
1.0
|
13.6
|
0.5
|
0.31
|
0.07
| | | | |
Sc
|
388
|
214
|
2292
|
14
|
0.17
|
0.09
| | | | |
Mn
|
94
|
57
|
602
|
5
|
0.16
|
0.09
| | | | |
Co
|
328
|
253
|
2281
|
24
|
0.1
|
0.08
| | | | |
Ni
|
160
|
84
|
1144
|
14
|
0.14
|
0.07
| | | | |
Ga
|
187
|
145
|
1194
|
12
|
0.2
|
0.1
| | | | |
Ge
|
13
|
2
|
51
|
9
|
0.24
|
0.06
| | | | |
Sr
|
175
|
76
|
736
|
16
|
0.20
|
0.10
| | | | |
Y
|
918
|
166
|
1609
|
40
|
0.60
|
0.10
| | | | |
Zr
|
1269
|
248
|
2462
|
81
|
0.50
|
0.10
| | | | |
Nb
|
474,314
|
123,606
|
253,661
|
11,699
|
1.9
|
0.5
| | | | |
Mo
|
13
|
3
|
20
|
0
|
0.6
|
0.1
| | | | |
Ba
|
178
|
138
|
1187
|
39
|
0.1
|
0.08
| | | | |
La
|
483
|
74
|
973
|
35
|
0.5
|
0.08
| | | | |
Ce
|
349
|
44
|
719
|
19
|
0.49
|
0.06
| | | | |
Nd
|
1034
|
185
|
1262
|
34
|
0.8
|
0.1
| | | | |
Sm
|
973
|
207
|
1145
|
27
|
0.8
|
0.2
| | | | |
Gd
|
611
|
137
|
725
|
19
|
0.8
|
0.2
| | | | |
Dy
|
582
|
133
|
818
|
28
|
0.7
|
0.2
| | | | |
Yb
|
454
|
75
|
950
|
31
|
0.48
|
0.08
| | | | |
Lu
|
967
|
137
|
2200
|
74
|
0.44
|
0.06
| | | | |
Hf
|
1334
|
288
|
2501
|
91
|
0.5
|
0.1
| | | | |
Ta
|
2973
|
749
|
812
|
33
|
3.7
|
0.9
| | | | |
Th
|
95
|
20
|
227
|
7
|
0.42
|
0.09
| | | | |
U
|
9
|
3
|
163
|
12
|
0.05
|
0.02
| | | | |
|
SE_Pyro6
| | | | | | | | | |
---|
n
|
5
| |
2
| |
5
| | | | | |
---|
|
Nb-pyr
|
Stdev
|
Fer
|
Stdev
|
Melt
|
Stdev
|
D Nb-pyr/melt SE6
| |
D fer/melt SE6
| |
---|
Li
|
3
|
–
|
–
|
–
|
10.3
|
0.2
|
0.25
|
–
|
–
|
–
|
Sc
|
62
|
9
|
70
|
51
|
2240
|
11
|
0.028
|
0.004
|
0.03
|
0.02
|
Mn
|
33
|
9
|
26
|
2
|
570
|
5
|
0.06
|
0.02
|
0.045
|
0.0003
|
Co
|
43
|
22
|
14
|
3
|
2191
|
24
|
0.02
|
0.01
|
0.006
|
0.001
|
Ni
|
13
|
5
|
–
|
–
|
1115
|
14
|
0.012
|
0.004
|
–
|
–
|
Ga
|
6.6
|
1.1
|
1.2
|
0.5
|
1286
|
19
|
0.0051
|
0.0009
|
0.001
|
0.0004
|
Ge
|
22
|
2
|
13
|
4
|
23.6
|
1.0
|
0.92
|
0.08
|
0.5
|
0.2
|
Sr
|
366
|
7
|
92
|
3
|
781
|
15
|
0.47
|
0.01
|
0.117
|
0.005
|
Y
|
555
|
20
|
1001
|
314
|
1539
|
30
|
0.36
|
0.02
|
0.7
|
0.2
|
Zr
|
319
|
39
|
1372
|
439
|
2300
|
45
|
0.14
|
0.02
|
0.6
|
0.2
|
Nb
|
398,834
|
6729
|
803,171
|
23,398
|
209,001
|
6675
|
1.91
|
0.07
|
3.8
|
0.2
|
Mo
|
5.7
|
0.5
|
11.9
|
0.6
|
47.8
|
1.0
|
0.12
|
0.01
|
0.25
|
0.01
|
Ba
|
98
|
4
|
1.7
|
0.5
|
1167
|
29
|
0.084
|
0.004
|
0.0015
|
0.0005
|
La
|
1439
|
109
|
343
|
143
|
1265
|
27
|
1.14
|
0.09
|
0.3
|
0.1
|
Ce
|
712
|
31
|
282
|
126
|
858
|
21
|
0.83
|
0.04
|
0.3
|
0.1
|
Nd
|
1824
|
125
|
1089
|
361
|
1504
|
32
|
1.21
|
0.09
|
0.7
|
0.2
|
Sm
|
1291
|
75
|
1119
|
353
|
1266
|
30
|
1.02
|
0.06
|
0.9
|
0.3
|
Gd
|
597
|
25
|
742
|
214
|
738
|
16
|
0.81
|
0.04
|
1.0
|
0.3
|
Dy
|
434
|
12
|
682
|
207
|
796
|
20
|
0.55
|
0.02
|
0.9
|
0.3
|
Yb
|
208
|
8
|
448
|
170
|
908
|
22
|
0.23
|
0.01
|
0.5
|
0.2
|
Lu
|
380
|
19
|
896
|
333
|
2128
|
47
|
0.18
|
0.01
|
0.4
|
0.2
|
Hf
|
484
|
63
|
1180
|
579
|
2343
|
53
|
0.21
|
0.03
|
0.5
|
0.2
|
Ta
|
4050
|
593
|
4490
|
497
|
985
|
18
|
4.1
|
0.6
|
4.6
|
0.5
|
Th
|
108
|
16
|
64
|
54
|
241
|
5
|
0.45
|
0.07
|
0.3
|
0.2
|
U
|
2.9
|
0.8
|
11
|
6
|
81
|
4
|
0.04
|
0.01
|
0.13
|
0.08
|
|
SE_Pyro2
| | | | | | | | | |
---|
n
|
2
| |
5
| | | | | | | |
---|
|
Fer
|
Stdev
|
melt
|
Stdev
|
D fer/melt SE2
| | | | | |
---|
Li
|
–
|
–
|
11.2
|
0.2
|
–
|
–
| | | | |
Sc
|
–
|
–
|
3.0
|
0.04
|
-
|
–
| | | | |
Mn
|
2.5
|
–
|
22.7
|
0.5
|
0.11
|
–
| | | | |
Co
|
1.3
|
0.4
|
32.6
|
0.4
|
0.04
|
–
| | | | |
Ni
|
–
|
–
|
85.6
|
3.3
|
–
|
–
| | | | |
Ga
|
–
|
–
|
4.4
|
0.2
|
–
|
–
| | | | |
Ge
|
2.6
|
–
|
17.6
|
0.3
|
0.15
|
–
| | | | |
Sr
|
15.6
|
1.9
|
123
|
1
|
0.13
|
–
| | | | |
Y
|
5.5
|
0.44
|
4.1
|
0.1
|
1.3
|
0.2
| | | | |
Zr
|
31
|
12
|
80
|
1
|
0.38
|
0.03
| | | | |
Nb
|
583,356
|
17,353
|
253,850
|
3380
|
2.3
|
0.9
| | | | |
Mo
|
10.4
|
0.9
|
52.3
|
0.9
|
0.2
|
0.007
| | | | |
Ba
|
0.7
|
0.2
|
13.5
|
0.4
|
0.05
|
0.01
| | | | |
La
|
1.6
|
0.2
|
2.55
|
0.04
|
0.6
|
0.1
| | | | |
Ce
|
2.5
|
0.3
|
3.8
|
0.1
|
0.67
|
0.08
| | | | |
Nd
|
3.4
|
0.4
|
2.5
|
0.1
|
1.3
|
0.2
| | | | |
Sm
|
8.8
|
0.9
|
5.5
|
0.1
|
1.6
|
0.2
| | | | |
Gd
|
3.1
|
0.4
|
1.8
|
0.1
|
1.7
|
0.2
| | | | |
Dy
|
2.5
|
0.3
|
1.7
|
0.1
|
1.5
|
0.2
| | | | |
Yb
|
1.8
|
0.1
|
1.9
|
0.1
|
1.0
|
0.1
| | | | |
Lu
|
1.7
|
0.2
|
1.9
|
0.1
|
0.86
|
0.06
| | | | |
Hf
|
1.2
|
0.6
|
3.0
|
0.1
|
0.41
|
0.04
| | | | |
Ta
|
39.6
|
0.8
|
13.5
|
0.1
|
2.9
|
1.3
| | | | |
Th
|
0.8
|
0.1
|
1.14
|
0.04
|
0.7
|
0.1
| | | | |
U
|
0.28
|
0.04
|
3.08
|
0.03
|
0.09
|
0.01
| | | | |
- Fer = Ca-Nb-fersmite, Nb-pyr = Ca-Nb-pyrochlore, melt = quenched melt, Ta—pyr = Ca- Ta-microlite, stdev = standard deviation (2 sigma)