From: Eu(III) and Am(III) adsorption on aluminum (hydr)oxide minerals: surface complexation modeling
Surface complexation reaction | log K | ||
---|---|---|---|
Corundum | γ-Alumina | Gibbsite | |
\(\equiv AlOH+{H}^{+}\leftrightarrow { \equiv AlOH}_{2}^{+}\) | 6.03 ± 0.25a | 8.50 ± 0.29a | 6.78 ± 0.29a |
\(\equiv AlOH\leftrightarrow \equiv Al{O}^{-}+{H}^{+}\) | − 7.47 ± 0.42a | − 9.20 ± 0.52a | − 10.10 ± 0.43a |
\(\equiv {Al}_{s}OH+{Eu}^{+3}\leftrightarrow \equiv {Al}_{s}O{Eu}^{+2}+{H}^{+}\) | N/A | N/A | N/A |
\(\equiv {Al}_{s}OH+{Eu}^{+3}+{H}_{2}O\leftrightarrow \equiv {Al}_{s}O{EuOH}^{+}+{2H}^{+}\) | − 1.54 ± 0.16 | 0.50 ± 0.08 | N/A |
\(\equiv {Al}_{w}OH+{Eu}^{+3}\leftrightarrow \equiv {Al}_{w}O{Eu}^{+2}+{H}^{+}\) | N/A | N/A | 3.25 ± 0.22 |
\(\equiv {Al}_{w}OH+{Eu}^{+3}+{H}_{2}O\leftrightarrow \equiv {Al}_{w}O{EuOH}^{+}+{2H}^{+}\) | − 5.45 ± 0.18 | − 5.03 ± 0.08 | − 5.10 ± 0.23 |
RMSE | 0.1978 | 0.1166 | 0.1799 |
R2 | 0.7804 | 0.9229 | 0.8282 |
Correlation coefficient | 0.146 | − 0.023 | − 0.124 |
\(\equiv AlOH+{Am}^{+3}+{H}_{2}O\leftrightarrow \equiv AlO{AmOH}^{+}+{2H}^{+}\) | − 3.91 ± 0.29 | − 2.36 ± 0.08 | N/A |
RMSE | 0.1907 | 0.1059 | N/A |
R2 | 0.7856 | 0.9323 | N/A |